AJ-
A lady moving to the USA is not required to be a "citizen" to obtain permanent residency. She can apply for a "permanent resident card" here and never be a citizen.
Your new wife can apply for a "Permanent Residence Card". But it is still considered "temporary" until she meets time living in the US requirements for true permanent residency.
I have been through this process with my former wife (My EX) who is a Swiss national. My children have two passports, Swiss and US. My former wife lived in the US for nearly 15 years before she decided to actually apply for US Citizenship because it was not a requirement for her to remain in the US.
Here is the actual ISCIS Link:
http://www.uscis.gov/portal/site/uscis/menuitem.5af9bb95919f35e66f614176543f6d1a/?vgnextoid=ddb2194d3e88d010VgnVCM10000048f3d6a1RCRD&vgnextchannel=4f719c7755cb9010VgnVCM10000045f3d6a1RCRD